GreensvilleJay has given you the correct answer. There might also be some tension from the impeller. One thing that I can't stress enough is not to put your hands anywhere near the impeller until it is loose. It can be jammed and if it springs loose and your hands are near it, you will get hurt. I suggest that you use a hammer to tap the impeller in the opposite direction of the way that it normally goes until it is free of the case. Presently it might be putting some sideward pressure on the shaft preventing the shaft's removal. This is one of those times that it would be easy for me to diagnose the issue if I were there but by long distance, I can only guess. No matter what you do, don't hammer on the shaft, because you might damage the gearbox at the front of the blower. When you get the shaft out and have the impeller in your hands, I suggest drilling the shaft area and putting in a grease fitting. I know that the grease isn't required, but it will keep any rust at bay on that section of the shaft where the impeller will spin freely when you break the shear pin, just like the front augers.
Are you planning on replacing the fan or just straightening it? Most likely it will need to be replaced since it will be out of balance and the blower will vibrate. The vibrations will not harm anything, but it will be annoying. Also, check your chain for any damaged or bent links. When my blower ate a rock, it destroyed the chain, and I didn't want to buy the expensive chain that Kubota uses, so I purchased a 10' box of number 40 chain and made up a bunch of them. I would replace them every year or two because they weren't the quality of the Kubota chain, but it also gave me a reason to check the rest of the rear end of the machine. I use chain bar oil on the chain for lubrication. Everyone seems to have their own particular choice of lubrication, and the important thing is that the chain is lubricated.
Let us know how it is coming along, and if you get stuck again, don't hesitate to ask more questions. We all learn from other mishaps and mistakes.